Hamotzi blesses God as the one who brings forth bread from the earth. It covers a meal that includes bread, so other food blessings are not needed for that meal. Said before eating bread, after washing the hands.
בָּרוּךְ אַתָּה יְיָ אֱלֹהֵינוּ מֶלֶךְ הָעוֹלָם הַמּוֹצִיא לֶחֶם מִן הָאָרֶץ
barukh atah adonai eloheinu melekh ha'olam hamotzi lekhem min ha'aretz
Blessed are You, Lord our God, King of the universe, who brings forth bread from the earth.